<?xml version="1.0" encoding="ISO-8859-1"?><article xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance">
<front>
<journal-meta>
<journal-id>1816-7950</journal-id>
<journal-title><![CDATA[Water SA]]></journal-title>
<abbrev-journal-title><![CDATA[Water SA]]></abbrev-journal-title>
<issn>1816-7950</issn>
<publisher>
<publisher-name><![CDATA[Water Research Commission (WRC)]]></publisher-name>
</publisher>
</journal-meta>
<article-meta>
<article-id>S1816-79502012000300003</article-id>
<title-group>
<article-title xml:lang="en"><![CDATA[Sand, salt and water in the Stampriet Basin, Namibia: calculating unsaturated zone (Kalahari dunefield) recharge using the chloride mass balance approach]]></article-title>
</title-group>
<contrib-group>
<contrib contrib-type="author">
<name>
<surname><![CDATA[Stone]]></surname>
<given-names><![CDATA[AEC]]></given-names>
</name>
<xref ref-type="aff" rid="A01"/>
<xref ref-type="aff" rid="A02"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname><![CDATA[Edmunds]]></surname>
<given-names><![CDATA[WM]]></given-names>
</name>
<xref ref-type="aff" rid="A01"/>
</contrib>
</contrib-group>
<aff id="A01">
<institution><![CDATA[,University of Oxford School of Geography and the Environment Oxford Water Futures Programme]]></institution>
<addr-line><![CDATA[Oxford ]]></addr-line>
<country>UK</country>
</aff>
<aff id="A02">
<institution><![CDATA[,University of Oxford School of Geography and the Environment Landscapes Dynamics Research Cluster]]></institution>
<addr-line><![CDATA[Oxford ]]></addr-line>
<country>UK</country>
</aff>
<pub-date pub-type="pub">
<day>00</day>
<month>00</month>
<year>2012</year>
</pub-date>
<pub-date pub-type="epub">
<day>00</day>
<month>00</month>
<year>2012</year>
</pub-date>
<volume>38</volume>
<numero>3</numero>
<fpage>367</fpage>
<lpage>378</lpage>
<copyright-statement/>
<copyright-year/>
<self-uri xlink:href="http://www.scielo.org.za/scielo.php?script=sci_arttext&amp;pid=S1816-79502012000300003&amp;lng=en&amp;nrm=iso&amp;tlng=en"></self-uri><self-uri xlink:href="http://www.scielo.org.za/scielo.php?script=sci_abstract&amp;pid=S1816-79502012000300003&amp;lng=en&amp;nrm=iso&amp;tlng=en"></self-uri><self-uri xlink:href="http://www.scielo.org.za/scielo.php?script=sci_pdf&amp;pid=S1816-79502012000300003&amp;lng=en&amp;nrm=iso&amp;tlng=en"></self-uri><abstract abstract-type="short" xml:lang="en"><p><![CDATA[Estimating groundwater recharge rates in the Stampriet Basin is important for assessing the sustainability of the groundwater resource both within south-east Namibia, and across the borders of this transboundary resource into Botswana and South Africa. The 65 000 km² basin contains a multi-layered aquifer system, of up to 9 superimposed aquifers, with a major upper unconfined and 2 major artesian levels. The majority of water abstraction (66%) is from the unconfined Kalahari Aquifer. This research investigates the direct recharge pathway through the dune-sand cover of the southern Kalahari dunefield which overlies ~80% of the basin. This is undertaken using established chloride mass balance methods within 4 unsaturated zone profiles (9 m to 11.5 m depth) from 2 regions of the basin. The results indicate that recent recharge rates are between 7 mmy-1 to 46 mmy-1, with profiles representing between 10 years and 30 years of rainfall infiltration. This is the first time that substantial direct (diffuse) recharge has been quantified for the Stampriet Basin, and this part of the southern Kalahari. These 4 profiles indicate potentially similar levels of spatial variability as seen in many other semi-arid, sand-rich unsaturated zones across the world. Further studies using the unsaturated zone should be employed in this region, to better inform our understanding of recharge mechanisms across the basin. The chloride mass balance technique provides information about the unsaturated zone, and important insights about recharge in various sand-covered regions of the basin for which very little is known, or is possible to determine using conventional water balance approaches. Direct recharge rates estimated in this way constitute a vital part of constraining the water balance of the basin, and particularly of the Kalahari Aquifer from which the majority of groundwater abstraction occurs.]]></p></abstract>
<kwd-group>
<kwd lng="en"><![CDATA[groundwater]]></kwd>
<kwd lng="en"><![CDATA[direct recharge]]></kwd>
<kwd lng="en"><![CDATA[chloride mass balance]]></kwd>
<kwd lng="en"><![CDATA[unsaturated zone]]></kwd>
<kwd lng="en"><![CDATA[Stampriet Artesian Basin]]></kwd>
<kwd lng="en"><![CDATA[Kalahari]]></kwd>
</kwd-group>
</article-meta>
</front><body><![CDATA[ <p><font face="Verdana, Arial, Helvetica, sans-serif" size="4"><b><a name="top"></a>Sand,    salt and water in the Stampriet Basin, Namibia: Calculating unsaturated zone    (Kalahari dunefield) recharge using the chloride mass balance approach</b></font></p>     <p>&nbsp;</p>     <p>&nbsp;</p>     <p><font face="Verdana, Arial, Helvetica, sans-serif" size="2"><b>AEC Stone<sup>I,    II, <a href="#back">*</a></sup>; WM Edmunds<sup>I</sup></b></font></p>     <p><font face="Verdana, Arial, Helvetica, sans-serif" size="2"><sup>I</sup>Oxford    Water Futures Programme School of Geography and the Environment, University    of Oxford, South Parks Road, Oxford, OX1 3QY, UK    <br>   <sup>II</sup>Landscapes Dynamics Research Cluster, School of Geography and the    Environment, University of Oxford, South Parks Road, Oxford, OX1, 3QY, UK    <br>   </font></p>     <p>&nbsp;</p>     <p>&nbsp;</p> <hr noshade size="1">     <p><font face="Verdana, Arial, Helvetica, sans-serif" size="2"><b>ABSTRACT</b></font></p>     ]]></body>
<body><![CDATA[<p><font face="Verdana, Arial, Helvetica, sans-serif" size="2">Estimating groundwater    recharge rates in the Stampriet Basin is important for assessing the sustainability    of the groundwater resource both within south-east Namibia, and across the borders    of this transboundary resource into Botswana and South Africa. The 65 000 km<sup>2</sup>    basin contains a multi-layered aquifer system, of up to 9 superimposed aquifers,    with a major upper unconfined and 2 major artesian levels. The majority of water    abstraction (66%) is from the unconfined Kalahari Aquifer. This research investigates    the direct recharge pathway through the dune-sand cover of the southern Kalahari    dunefield which overlies ~80% of the basin. This is undertaken using established    chloride mass balance methods within 4 unsaturated zone profiles (9 m to 11.5    m depth) from 2 regions of the basin. The results indicate that recent recharge    rates are between 7 mmy<sup>-1</sup> to 46 mmy<sup>-1</sup>, with profiles representing    between 10 years and 30 years of rainfall infiltration. This is the first time    that substantial direct (diffuse) recharge has been quantified for the Stampriet    Basin, and this part of the southern Kalahari. These 4 profiles indicate potentially    similar levels of spatial variability as seen in many other semi-arid, sand-rich    unsaturated zones across the world. Further studies using the unsaturated zone    should be employed in this region, to better inform our understanding of recharge    mechanisms across the basin. The chloride mass balance technique provides information    about the unsaturated zone, and important insights about recharge in various    sand-covered regions of the basin for which very little is known, or is possible    to determine using conventional water balance approaches. Direct recharge rates    estimated in this way constitute a vital part of constraining the water balance    of the basin, and particularly of the Kalahari Aquifer from which the majority    of groundwater abstraction occurs.</font></p>     <p><font face="Verdana, Arial, Helvetica, sans-serif" size="2"><b>Keywords:</b>    groundwater, direct recharge, chloride mass balance, unsaturated zone, Stampriet    Artesian Basin, Kalahari</font></p> <hr noshade size="1">     <p>&nbsp;</p>     <p>&nbsp;</p>     <p><font face="Verdana, Arial, Helvetica, sans-serif" size="3"><b>Introduction</b></font></p>     <p><font face="Verdana, Arial, Helvetica, sans-serif" size="2">The Stampriet Basin    (often referred to as the Stampriet Artesian Basin, SAB, whether or not the    artesian layers are being considered) is a multi-layered aquifer covering ~65    000 km<sup>2</sup> in Namibia (JICA, 2002; Tredoux et al., 2002) and extending    an unknown distance into Botswana and South Africa (<a href="/img/revistas/wsa/v38n3/03f01.jpg">Fig.    1</a>). It is a vital resource in this semi-arid part of the southern Kalahari,    where surface water is scarce and unreliable. Groundwater supports domestic    use of water and also agriculture (including the practice of irrigation farming    and livestock), which is the main contributor to job creation and the economy    of this region (Christelis and Struckmeier, 2001). As a transboundary resource    its sustainability is an important issue for continuing human and economic development,    not only in the Namibian portion of the aquifer, but in the largely unstudied    and undeveloped portions within eastern Botswana and the northern reaches of    the Northern Cape of South Africa. Declining artesian aquifer water levels,    of ~5 cmy<sup>-1</sup> have been reported (JICA, 2002) and establishing sustainable    management of this aquifer requires assessment of present-day, Recent reassessment    of the recharge behaviour of the northwest fringes of the SAB by Tredoux et    al. (2002) and Kirchner et al. (2002) (<a href="/img/revistas/wsa/v38n3/03f01.jpg">Fig. 1</a>)    suggests that recharge via faults and karst features (focused recharge) is the    dominant mechanism of recharge in this north-west portion of the SAB, and specifically    to the Auob artesian layer (<a href="/img/revistas/wsa/v38n3/03f01.jpg">Fig. 1</a>, karst features    are in Weissrand and NW, seen as regions of dense drainage lines). By extension,    considering that the flow direction in this multilayered aquifer basin is north-west    to south-east, it is assumed by those authors that focused recharge through    sinkholes and faults is the major recharge source for the entire basin.</font></p>     <p><font face="Verdana, Arial, Helvetica, sans-serif" size="2">This paper provides    the first application of the chloride mass balance (CMB) technique (Edmunds    et al., 1988) in the unsaturated (or vadose) zone (USZ) above the SAB to address    whether direct (or diffuse) recharge through the Kalahari linear sand-dune cover    is occurring as potential recharge to groundwater. CMB approaches are a well-established    method for estimating direct recharge in arid and semi-arid regions (see Scanlon    et al., 2006 for a recent review). We note that without large-scale drilling    at these sites, and borehole level monitoring from unconfined and confined layers    it is not possible to assess what happens to the water beneath the sampled depth    of the unsaturated zone within the Kalahari dunes. Where dated using optically    stimulated luminescence dating, often to full dune depth, the Kalahari linear    dunes are of Quaternary age, with those at the western margin (toward Mariental)    &lt; 50 ka (from samples at the base of dunes), and ~ 186 ka &plusmn; 15 ka    at 6.5 m to 8.5 m depth east of Stampriet (Stone and Thomas, 2008). In Botswana    there has been a lively debate over the past century as to whether rainfall    is able to penetrate the depth of the Kalahari sand dunes (representing the    USZ) to reach underlying aquifers. For example, whilst Foster et al. (1982)    concluded that direct recharge was unlikely for sands exceeding 4 m in thickness,    Gieske (1992), Gieske et al. (1995), Selaolo et al. (1995), Selaolo (1998) and    De Vries et al. (2000) have all shown that recharge may be occurring in thicknesses    of 10 m and more. This contrasts with earlier ideas from a number of authors    who thought that diffuse recharge could not occur through sand thickness of    &gt; 6 m (e.g. Martin, 1961; Boocock and Van Straten, 1962; Foster et al., 1982;    De Vries, 1984).</font></p>     <p><font face="Verdana, Arial, Helvetica, sans-serif" size="2">In the present    study 4 USZ dune cores have been sampled above the SAB; in the SE of the basin,    a core to the south and a core to the north of the Auob River and near Stampriet    a pair of cores (~5 m apart to investigate small-scale site similarity) (<a href="/img/revistas/wsa/v38n3/03f01.jpg">Fig.    1</a>, hexagons). As the dunefield mantle covers 80% of the surface of the basin,    infiltration through the sands (USZ) representing the direct (or diffuse) recharge    mechanism to those underlying aquifer levels with a hydrological connection,    is a very important regional parameter, and has currently not been addressed    for this basin.</font></p>     <p><font face="Verdana, Arial, Helvetica, sans-serif" size="2"><b>Location</b></font></p>     <p><font face="Verdana, Arial, Helvetica, sans-serif" size="2">The SAB lies in    the south-east of Namibia, between ~22º S to 26º S, extending as far west as    17º 30'E near Kalkrand, and extending an uncharted distance into Botswana and    the north of the Northern Cape, South Africa, to the east (<a href="/img/revistas/wsa/v38n3/03f01.jpg">Fig.    1</a>). The basin slopes slightly from north-west to the south-east, with a    highest elevation of 1 350 m amsl at the north and north-west boundary and lowest    elevation of 950 m amsl in the south-east near Mata-Mata and Ko&eacute;s (<a href="/img/revistas/wsa/v38n3/03f01.jpg">Fig.    1</a> - inset with topography). Geomorphologically, the region is dominated    by the southern Kalahari dunefield (<a href="/img/revistas/wsa/v38n3/03f01.jpg">Fig. 1</a> -    inset with geomorphology), which covers ~80% of the surface of the basin, with    linear dunes oriented broadly NW-SE. The dunefield extends about 20 km west    of the Auob River, and gives way to exposed bedrock in the south-west from Ko&eacute;s    up to Mariental, and again in the north-west. There is a distinctive gap in    the dunes north-west of Stampriet, which lies between upper reaches and dry    tributary streams of the Auob River (<a href="/img/revistas/wsa/v38n3/03f01.jpg">Fig. 1</a> a    geomorphological inset). Surface drainage follows the elevation pattern, via    ephemeral rivers, the Auob, Olifants and Nossob Rivers, and the former water    courses and tributaries also describe this trend. The ephemeral rivers only    flow in periods of high rainfall, but remain endorheic within the Orange River    basin. The Auob was observed to flow as far as ~60 km from the border with South    Africa in April 2011 during fieldwork.</font></p>     ]]></body>
<body><![CDATA[<p><font face="Verdana, Arial, Helvetica, sans-serif" size="2">Mean annual rainfall    varies across the basin with values of ~240 mmy<sup>-1</sup> at Leonardville,    205 mmy<sup>-1</sup> at Aranos, 190 mmy<sup>-1</sup> at Stampriet and 175 mmy<sup>-1</sup>    at Ko&eacute;s. It is estimated by the local farmers that the 2010-2011 rainy    season experienced about 3 times the annual average precipitation. The last    time rainfall was this high was during the mid-1970s (1974 and 1976), with 600    mmy<sup>-1</sup> recorded at Leonardville for 1974. Another good rainfall season    occurred in 1999/2000, in which lakes were forming in the dune areas east of    Kalkrand (Kirchner, 2012). In 2011, during sampling, there was water in pans    just east of Stampriet. Levels of mean annual potential evaporation are high    in the region, and estimated to be between 3 000 mmy<sup>-1</sup> in the north    to 3 500 mmy<sup>-1</sup> in the south. Rainfall is characteristically episodic    in semi-arid regions, including southern Africa, which means that recharge is    also often similarly episodic (Van Wyk, 2012).</font></p>     <p><font face="Verdana, Arial, Helvetica, sans-serif" size="2"><b>Hydrogeology</b></font></p>     <p><font face="Verdana, Arial, Helvetica, sans-serif" size="2">A detailed geological    reinterpretation of earlier reports (Range, 1914; Martin, 1962; Heath, 1972)    and new boreholes drilled during the JICA (Japan International Cooperation Agency)    study (1999-2001) has been undertaken by Miller (2000) and JICA (2002). <a href="/img/revistas/wsa/v38n3/03t01.jpg">Table    1</a> illustrates a simplified geological stratigraphy and corresponding hydrogeological    classification, and <a href="/img/revistas/wsa/v38n3/03f02.jpg">Fig. 2</a> illustrates 3 geological    and inferred hydrogeological cross sections for the region. The reinterpretation    confirmed the multi-layer nature of the aquifer, with water being contained    in the Nossob, Auob and Kalahari members. It also illustrated the complexity    of the stratigraphy, with erosional contacts, faults and dolerite intrusions,    which means that the aquifer units do not overlie each other in all regions    of the basin (JICA, 2002). Erosion prior to the deposition of the Kalahari Basin    formed channels, which in the south-eastern region of the basin reached the    lowermost Auob levels (Miller, 2008). The implication is that any hydraulic    linkage between the aquifer units is also complex. Across much of the basin    the Auob Aquifer is clearly confined. This is demonstrated in regions such as    Olifantswater in the north-west of the basin, where piezometric data suggest    a lack of direct hydraulic linkage between the Kalahari and Auob Aquifers (see    Tredoux et al., 2002 and JICA, 2002), and may be the case over much of the basin.    However, there may be some connection where the erosion channels occur and where    faults and dolerite intrusions exist.</font></p>     <p><font face="Verdana, Arial, Helvetica, sans-serif" size="2">Good progress has    been made in understanding the recharge mechanisms in the north-western and    western part of the basin. The combination of piezometric data, geological sections    that indicate the Auob and Nossob artesian members wedge out at the north-west    and western edge of the SAB and the observation of sinkhole structures in near    Uhlenhorst and on the Wiessrand near Mariental (indicated as dense drainage    lines on geomorphology inset, <a href="/img/revistas/wsa/v38n3/03f01.jpg">Fig. 1</a>), and the    observations of the 1960 cloudburst and infiltration by Schalk (1961) have led    Tredoux et al. (2002) to suggest focused recharge through the sinkholes and    geological fault lines as being the most important in that region. However,    as Tredoux et al. (2002) note, there is poor understanding of the recharge mechanisms    elsewhere in the basin. Radiocarbon ages taken from Kalahari, Auob and Nossob    Aquifers are all relatively high, with ages &lt; 2000 years along the north-western    part of basin and Nossob River (e.g. JICA, 2002). JICA (2002) also report finding    tracers of tritium in boreholes into the Kalahari Aquifer (and one into the    Auob Aquifer) and suggest it is possible that more recent water has become blended    into groundwater and also note that chemical reactions within the groundwater    system can lead to overestimations of radiocarbon ages. It has remained difficult    to come to definitive conclusions about levels of recharge to upper layers and    artesian layers.</font></p>     <p><font face="Verdana, Arial, Helvetica, sans-serif" size="2"><b>Sample sites    and methods</b></font></p>     <p><font face="Verdana, Arial, Helvetica, sans-serif" size="2">Linear dunes (making    up the uppermost USZ) were sampled in 2 regions (<a href="/img/revistas/wsa/v38n3/03f01.jpg">Fig.    1</a>, hexagons), with cores taken from bare patches of sand, and away from    dense vegetation cover, with particular care to sample as far as possible from    small trees (at least 30 m), to reduce the chance of striking roots and locally    high areas of evapotranspiration. Of course, these localised effects need to    be considered, when estimating the overall regional recharge pattern. In the    south-east of the basin core KAL1/1 was taken at 25&deg;29'31.65" S, 19º40'    52.78'' E, 3 km north of the Auob River valley, and core KAL11/2 was taken at    25º44'05.42'' S, 19º40'56.90'' E, 24km south of the Auob River valley. In the    centre of the SAB, at Bysteek Farm, near Stampriet (20 km east/north-east) 2    neighbouring cores were extracted (~5 m apart), at 24º16'57.17'' S, 18º35'41.08''    E. The second (KAL11/4) was closer (&lt;1 m) to a clump of grass <i>(Stipagrostis    amabilis).</i> The vegetation on the Kalahari dunes includes small 2 m to 3    m <i>Acacia</i> species such as camel thorn <i>(Acacia erioloba),</i> shrubs    such as <i>Rhigozum trichotomum,</i> and prevalent grasses (which thrive after    the rainy season), including <i>Stipagrostis amabilis, Schmidtia kalahariensis</i>    and <i>Aristida congesta.</i> Tsamma melon was also observed <i>(Citrullus lanatus),</i>    particularly at Site KAL11/2. Cores into the sand dunes were taken by hand auger    (Edmunds and Gaye, 1994) at 20 cm, 30 cm or 50 cm intervals, down to 9.2 m or    &gt;11 m depth. Samples were transferred from an aluminium compression sampling    head into 15 cm long (representing the vertical plane) sections of opaque drainpipe    (as employed by Stone and Thomas, 2008) with tight-fitting lids and sealed tightly    to seal in moisture during transit to the laboratory.</font></p>     <p><font face="Verdana, Arial, Helvetica, sans-serif" size="2">The superficial    geology comprises virtually carbonate-free linear dune sands, standing between    15 m to 25 m above the inter-dune surface. It is possible to infer the geology    underlying the sampled sites from nearby boreholes, sampled and described during    the JICA (2002) project. In the southeast, Borehole J8, 25 km west of KAL11/1    and KAL11/2, at Tweerivier (without dune cover) indicates that our sampled dune    sands are underlain by Kalahari beds (~140 m thick), and the contact with dunes    is a calcrete layer (~3 m thick). The calcrete is moderately karsted, implying    that water could drain through the karst solution features, down into the underlying    conglomerate (~9 m), sandy calcrete (~7 m) and unsorted sandstone (~110 m thick).    The farm boreholes at Terra Rouge Farm, where KAL11/1 and KAL11/2 were sampled,    indicate that the water table is reached at ~50 m depth. Near Stampriet, at    Bysteek Farm, the nearest JICA borehole (J5) is 20 km west, where the Kalahari    beds have wedged out, exposing the upper Rietmond Member (<a href="/img/revistas/wsa/v38n3/03t01.jpg">Table    1</a>). However, we can infer from local exposures on Bysteek Farm that there    is a shallow Kalahari bed unit (perhaps 20 m to 30 m) including patches of the    conglomerate. Locally, the water table is much closer to the surface here, with    some flooding in some of the inter-dune pans in the region, including ~2 km    south-west of the cored dune, observed during sampling in April, 2011. The ponding    in pans appears to be a patchy process, as also reported by Schalk (1961) in    the Uhlenhorst region in 1960 and all across the region by Martin (1961). The    farmer at Bysteek reports that the boreholes are ~30 m deep, again suggesting    that the Kalahari beds (unconfined aquifer layer, <a href="/img/revistas/wsa/v38n3/03t01.jpg">Table    1</a>) do underlie the dunes here, rather than at Stampriet, where the Kalahari    beds are absent and water is artesian. The base of the Kalahari beds contains    fluviatile gravels, which are extensively cemented by calcrete, in some places    shallow and weathered (Miller, 2000; JICA, 2002; Miller, 2008). In the north-west    this is underlain by Kalkrand Basalt, whilst in the east this is underlain in    some places by the Whitehill formation, and elsewhere this directly overlies    the Upper Rietmond member. The Upper Rietmond contains sandstone layers of different    colours and calcareous contents (over ~40 m). Underneath the Upper Rietmond    member, and above the Auob Aquifer sits the Lower Rietmond member (~10 m), composed    of siltstones and shales, and considered to be impermeable. Therefore at this    site, it is unlikely that direct recharge through the sand dunes would replenish    the Auob Aquifer, unless there is hydrological connection at a fault line.</font></p>     <p><font face="Verdana, Arial, Helvetica, sans-serif" size="2">Representative    subsamples of each sample were used to determine moisture content, using a gravimetric    method, drying at 110ºC for 48 h (Black, 1965) and particle size, using a laser    granulometer with statistics calculated using GRADISTAT (Blott and Pye, 2000)    and applying the Folk and Ward (1957) method. For chloride analysis the pore    water was extracted from 30 g of sand-dune material by elutriation with 12 ml    of ultrapure, deionised water (Edmunds et al., 1988; Gates et al., 2008), placed    in a shaker tray for 1 h and centrifuged, before filtering the supernatant at    0.2 um. The chloride concentrations of the elutriated samples were analysed    at the Oxford Centre for the Environment using ion chromatography, and analytical    precision was ~5%, based on repeat measurements of the same elutriated solution    on different days, and the detection limit was ~0.1 mgl<sup>-1</sup>, based    on measurements of standard solutions. Sample reproducibility was ~1% to 22%    on the basis of multiple elutriations of a number of samples, indicating a reasonable    degree of sample homogeneity (wherever multiple elutriations were made, the    average value for chloride concentration is used).</font></p>     <p><font face="Verdana, Arial, Helvetica, sans-serif" size="2">Using the steady-state    chloride mass balance (CMB) approach, average direct recharge <i>(R<sub>d</sub>)</i>    through the sampled depth of the unsaturated zone is given by the following    equation (Allison and Hughes, 1978):</font></p>     <p align="center"><img src="/img/revistas/wsa/v38n3/03x01.jpg"></p>     ]]></body>
<body><![CDATA[<p><font face="Verdana, Arial, Helvetica, sans-serif" size="2">where:</font></p>     <blockquote>        <p><font face="Verdana, Arial, Helvetica, sans-serif" size="2"><i>P</i> is the      long-term average annual precipitation of the region</font></p>       <p><font face="Verdana, Arial, Helvetica, sans-serif" size="2"><i>C<sub>p</sub></i>      is the mean concentration of chloride in rainfall</font></p>       <p><font face="Verdana, Arial, Helvetica, sans-serif" size="2"><i>C<sub>d</sub></i>      is the mean chloride from dry deposition <i>(C<sub>p</sub></i> and <i>C<sub>d</sub></i>      can be considered together as total deposition (TD))</font></p>       <p><font face="Verdana, Arial, Helvetica, sans-serif" size="2"><i>C<sub>s</sub></i>      is the mean concentration of chloride in the pore waters in the unsaturated      zone</font></p> </blockquote>     <p><font face="Verdana, Arial, Helvetica, sans-serif" size="2">This uses the fact    that chloride is an inert tracer for moisture in the sand and further details    on the theoretical basis of the chloride mass balance method can be found elsewhere    (Allison and Hughes, 1978; Edmunds et al., 1988). The CMB method integrates    recharge at a given site over many years, based on the assumption of steady-state    conditions, transmission of water via diffuse (piston) flow and that a representative    average for rainfall chemistry (C<sub>p</sub>) can be ascertained. C<sub>p</sub>    is the largest source of uncertainty in the calculations (Scanlon, 2000) and    is problematic for the SAB region of Namibia, as no such data have yet been    recorded. However, inferences can be made from 2 extensive projects in neighbouring    Botswana (GRES I and GRES II, Beekman et al., 1996a; b; Selaolo, 1998), which    yield comprehensive maps of the spatial distribution of total chloride deposition    up to the border with Namibia. Values for precipitation for the 2 study sites    in the SAB are taken from the Namibian Meteorological Service Records from Stampriet    (from 1927 to 2002), Koes (from 1951 to 2004) and from farmer Pieter M&ouml;ller    at Terra Rouge (from 1993 to 2010).</font></p>     <p><font face="Verdana, Arial, Helvetica, sans-serif" size="2">It is also possible    to calculate the travel time (t) represented by the chloride at a specified    depth (z), assuming that cumulative chloride is proportional to time (Cook et    al., 1992). The time at a given depth (z) is calculated as:</font></p>     <p align="center"><img src="/img/revistas/wsa/v38n3/03x02.jpg"></p>     <p><font face="Verdana, Arial, Helvetica, sans-serif" size="2">where:</font></p>     ]]></body>
<body><![CDATA[<blockquote>        <p><font face="Verdana, Arial, Helvetica, sans-serif" size="2"><i>t</i> represents      time</font></p>       <p><font  size="2">&#952;</font><font face="Verdana, Arial, Helvetica, sans-serif" size="2">      is volumetric moisture content</font></p>       <p><font face="Verdana, Arial, Helvetica, sans-serif" size="2">The other variables      are defined as in Eq. (1) (Tyler et al., 1996)</font></p> </blockquote>     <p>&nbsp;</p>     <p><font face="Verdana, Arial, Helvetica, sans-serif" size="3"><b>Results and    discussion</b></font></p>     <p><font face="Verdana, Arial, Helvetica, sans-serif" size="2"><b>Vertical profiles</b></font></p>     <p><font face="Verdana, Arial, Helvetica, sans-serif" size="2"><a href="/img/revistas/wsa/v38n3/03f03.jpg">Figure    3</a> illustrates the sediment texture, moisture contents and chloride concentrations    of the 4 profiles. All profiles are relatively homogenous sands, dominated by    unimodal, moderately sorted to moderately well-sorted medium sand, with only    small textural variations with depth. There is a trend of increasing fine sand    and silt content (and less well sorted) with depth. This is most pronounced    in KAL11/2 which below 5 m contains poorly-sorted medium sand, with 2 lenses    of coarse silty medium sand (10% to 13% silt) towards the base. In both KAL11/3    and KAL11/4 the sediment changes from moderately sorted, to poorly sorted medium    sand at 11 m, with small increases in silt (to 9%).</font></p>     <p><font face="Verdana, Arial, Helvetica, sans-serif" size="2">Moisture contents    are low, ranging from 0.9% to 4.7%, and all the profiles are above the water    table. At the sites of KAL11/1 and KAL11/2 the farm boreholes would suggest    that the water table lies at ~50 m depth, whilst at the site of the neighbouring    cores (KAL11/3 and KAL11/4) the water table (perched or otherwise) may lie just    beneath the 15 m to 20 m high dunes, with localised standing surface water within    a 2 km radius. However, it is also possible that the localised standing water    may simply represent low permeability in the pan. In KAL11/1 there is an upper    (2 m) zone of fluctuating moisture, which would suggest that this is above the    zero-flux plane. Below this is a trend of increasing moisture with depth to    2.8%. In KAL11/2 there is a thicker (~4.5 m) fluctuating zone between 3.7% and    2.3% before a rapid drop down to 0.8% at a depth of 5.2 m, below which an average    of 1.4% is established. This transition from a moister upper section to a drier    lower section does not coincide with a transition in sediment texture (<a href="/img/revistas/wsa/v38n3/html/03f03.htm">Fig.    3b</a>). The neighbouring cores (KAL11/3 and KAL11/4) describe a very similar    moisture-depth relationship, with 2 noticeable differences. The first is the    drier uppermost sample of KAL11/4 (that is not seen in KAL11/3), which could    be related to different levels of surface disturbance to the sand in the upper    0.5 m. The second is a deep zone of reduced moisture content in KAL11/3 from    11 m depth that is not seen in KAL11/4. It is possible that a comparable region    of decreased moisture content in KAL11/4 lies beneath the maximum sampling depth    of 11.5 m (limit imposed by available hand-auguring equipment). The dune contains    small topographical variations along the crest and it is expected that some    variations in dune thickness may occur in horizontal dimension. The trend in    the Stampriet cores is of an increase of moisture with depth to 4.7% between    6 m to 7 m and then a slightly lower and more uniform moisture content for the    next 3.5 m (before KAL11/3 encounters the drier basal unit). There is no consistent    correspondence between the small changes in lithology and moisture content,    such as sediment sorting, or the percentage of silt in the sample, contrary    to what has been demonstrated by various authors (Tandia, 1990; Gaye and Edmunds,    1996; De Vries et al., 2000).</font></p>     <p><font face="Verdana, Arial, Helvetica, sans-serif" size="2">Concentrations    of chloride in these profiles vary from a minimum of 1.7 mgl<sup>-1</sup> (at    4 m in KAL11/4) to 240 mgl<sup>-1</sup> (at the base of KAL11/3). The 2 cores    from the south-east of the SAB (KAL11/1, KAL11/2), tend to have higher steady-state    averages than the neighbouring cores near Stampriet (KAL11/3, KAL11/4), which    experience larger magnitude fluctuations (<a href="/img/revistas/wsa/v38n3/03f03.jpg">Fig. 3</a>).    There are considerable differences in shape and concentrations of chloride in    the 4 profiles, which is a common finding for semi-arid unsaturated zone chloride    profiles (Scanlon et al., 2006). This is observed, for example in southern Australia    (Sharma and Hughes, 1985; Cook et al., 1989), Western Australia (Allison, 1988),    Senegal (Edmunds and Gaye, 1994; Gaye and Edmunds, 1996), NE Nigeria (Edmunds    et al., 1999), eastern Botswana (Beekman et al., 1996b; Selaolo, 1998; De Vries    et al., 2000) and northern China (Gates et al., 2008). Spatial variability has    been found to occur at the scale of a groundwater basin and also within small    subregions (~ 0.5 km<sup>2</sup>) near Louga in Senegal (Edmunds and Gaye, 1994).    The variations in chloride concentration with depth in profiles has been related    to variable inputs of chloride into the profile (not including the mixing zone)    that correspond to different climatic periods (Edmunds et al., 1988).</font></p>     ]]></body>
<body><![CDATA[<p><font face="Verdana, Arial, Helvetica, sans-serif" size="2">KAL11/4 is the    only core to show a surface peak of chloride (~200 mgl<sup>-1</sup>). Surface    peaks in chloride are widely seen in arid and semi-arid environments, where    evaporation and transpiration processes actively remove moisture and increase    the concentration of solutes (Phillips, 1994; Scanlon, 1991; Stone, 1992). This    core site was closest to vegetation, encountering some small rootlets of <i>Stipagrostis    amabilis</i> as deep as 3 m, which suggests that the zone above 4 m may represent    the mixing zone at this site. The uppermost sample (0.55 m) has a concentration    4 times greater than that at 1.05 m. It has previously been noted that the upper    1 m in dryland profiles can represent a separate zone, or reservoir of chloride    within the mixing layer (Cook et al., 1992). This is thought to relate to solutes    within occluded pore spaces, which do not contribute to water flowing more freely.    This would tend to be measured when using elutriation to extract the pore moisture    (via dilution), and has been shown to be present in elutriated samples and absent    in sub-samples of the same material for which moisture was extracted simply    by centrifugation (Edmunds et al., 1992). However, the neighbouring core (KAL11/3)    does not have this peak, which again reflects the variation between profiles,    and the absence of absolute replicates of chloride profiles discussed above.    In addition, the location is 4 m further from the <i>Stipagrostis amabilis</i>    which may be indicative of the localised influence of vegetation. Without more    detailed field-based observation, or laboratory-based analysis and testing it    is not possible to evaluate the potential influence of unstable wetting fronts    and fingered flow (e.g. Hill and Parlange, 1972; Selker et al., 1992). In the    experience of WM Edmunds, such features tend to propagate over the top ~50 cm    and below this tend to homogenise and approximate piston flow.</font></p>     <p><font face="Verdana, Arial, Helvetica, sans-serif" size="2">The base of KAL11/3    contains a zone of higher chloride concentration below 10.3 m (rising from an    average of ~7 mgl<sup>-1</sup> to &gt;200 mgl<sup>-1</sup> by 11.5 m), starting    1 m above the zone of low moisture (&lt; 1.7%). Neither chloride nor moisture    features are seen in the adjacent core (KAL11/4), which is difficult to explain    definitively without additional profiles, and again indicates the frequent lack    of direct replication in tracer profile studies (Edmunds and Gaye, 1994). It    is difficult to explain this profile without additional data from the sediment    below that sampled. It is unlikely to be an active capillary fringe in view    of the lower moisture contents, but may represent a former incursion, or represent    residual geological artefacts (e.g. former surface feature, where water ponded,    before further dune accumulation has occurred above). There is a small change    in sedimentology with an increase in the silt content from 3% to 9% between    10.3 m to 11.8 m (also reflected in sediment sorting changing from moderately    sorted to poorly sorted for the lower 3 samples, at 11.2 m to 11.8 m depth).</font></p>     <p><font face="Verdana, Arial, Helvetica, sans-serif" size="2">By contrast to    the Stampriet profiles (KAL11/3 and 11/4) the cores from Region 1 (KAL11/1 and    11/2) both contain a region of higher chloride mid-way down the profile. In    KAL11/1 this occurs from 2.1 m to 4.7 m depth, in a broadly higher peak of Cl    (concentrations are above 35 mgl<sup>-1</sup>) and peaking at 65 mgl<sup>-1</sup>    at 3.1 m depth. In KAL11/2 there is a deeper and more abrupt increase in chloride    from 14 mgl<sup>-1</sup> to 164 mgl<sup>-1</sup>between 4.6 m and 5.2 m depth,    before returning to lower values (that fluctuate around an average of 50 mgl<sup>-1</sup>)    over the bottom 4 m of the core (<a href="/img/revistas/wsa/v38n3/html/03f03.htm">Fig. 3b</a>).    Again these differences in the chloride-depth profiles between cores reflect    the site-to-site differences that are widely observed in other tracer studies.    It is again most likely that these peaks again relate to changing chloride inputs    that reflect fluctuating climatic conditions (Edmunds et al., 1988).</font></p>     <p><font face="Verdana, Arial, Helvetica, sans-serif" size="2">All 4 cores exhibit    a broad inverse trend between pore moisture chloride concentration and sample    moisture content of the sample. This is the opposite of the trend observed in    Senegal profiles by Gaye and Edmunds (1996), but the same as the trend in profiles    from the Chihahuan Desert presented by Scanlon (1991). Many authors have attributed    variations in moisture content within cores to variations in sediment texture.</font></p>     <p><font face="Verdana, Arial, Helvetica, sans-serif" size="2">However, in these    cores not only is there very little variation in sediment texture, there is    no consistent relationship observed between moisture content and textural parameters    such as silt component or sediment sorting (in KAL11/1 below the mixing zone,    moisture increase tracks a reduction in sediment sorting, and a small increase    in silt, whilst in KAL11/2, KAL11/3 and KAL11/4 the reductions in sorting and    small increases in silt are not accompanied by unidirectional changes in moisture    content).</font></p>     <p><font face="Verdana, Arial, Helvetica, sans-serif" size="2"><b>Recharge rates</b></font></p>     <p><font face="Verdana, Arial, Helvetica, sans-serif" size="2">There are as yet    no local measurements of rainfall chemistry for the SAB from which to input    into Eq. (1) for calculating recharge. The best estimates come from extending    the spatial distribution of rainfall chloride compiled for Botswana from an    observation network (compiled from long-term regional monitoring and intensive    local-scale observations) during the detailed GRES I and GRES II studies (Beekman    et al., 1996a; b). For total deposition <i>(C + Cd)</i> a value of between 150    mgm<sup>-2</sup>y<sup>-1</sup> and 350 mg-m<sup>-2</sup>-y<sup>-1</sup> is indicated    for the SAB region, with a best estimate for an average input over time of 250    mg-m<sup>-2</sup>-y<sup>-1</sup> (following the approach of De Vries et al.,    2000 for the central Kalahari in Botswana). This equates to a chloride concentration    in rainfall of 1.4 mgl<sup>-1</sup> for the south-east (KAL11/1 and KAL11/3)    (with mean rainfall of 175 mmy<sup>-1</sup>) and 1.3 mgl<sup>-1</sup> for Stampriet    (KAL11/3 and KAL11/4) (with a mean rainfall of 190 mm-y<sup>-1</sup>). Conservative    error margins of 0.4 mgl<sup>-1</sup> are applied to these estimates. These    values are very close to the minimum concentration of dune moisture chloride    (C<sub>s</sub>) measured in the profiles and applying these error margins captures    the regional variations observed in the nearby Northern Cape region of South    Africa, where sites were monitored between 2003 and 2009 (including measurements    for early, peak and dry rainfall season) by Van Wyk et al. (2011), and the value    of 2.4 mgl<sup>-1</sup> applied by Adams et al. (2004) for the central Namaqualand    region of South Africa.</font></p>     <p><font face="Verdana, Arial, Helvetica, sans-serif" size="2">Using the steady-state    average of chloride concentrations for the whole profile for each core, recharge    rates range from 7 mm-y<sup>-1</sup> &plusmn; 2 mmy<sup>-1</sup> to 46 mm-y<sup>-1</sup>    &plusmn; 14 mmy<sup>-1</sup> (<a href="/img/revistas/wsa/v38n3/03t02.jpg">Table 2</a>). For KAL11/4    this is based on the steady-state average beneath the mixing zone, interpreted    to be influenced by the localised grassy vegetation (exclusion of the mixing    as illustrated by Edmunds (2001) and employed by many authors, including Gates    et al., 2008). In KAL11/3, the steady-state average is calculated above the    capillary zone, to capture solely the USZ. The observed variation in recharge    rates between cores is not unusual within a dunefield, or an even smaller region,    for example 0.5 km<sup>2</sup> near Louga, Senegal (Edmunds and Gaye, 1994).</font></p>     <p><font face="Verdana, Arial, Helvetica, sans-serif" size="2">The residence times    indicated for moisture in each profile in <a href="/img/revistas/wsa/v38n3/03t02.jpg">Table 2</a>    have been calculated using Eq. (2) (Cook et al., 1992; Tyler et al., 1996).    These represent 13 to 33 years (<a href="/img/revistas/wsa/v38n3/03t02.jpg">Table 2</a>). This    covers a period of time in which the mean climate has varied. At Stampriet years    with above-average rainfall include 1985, 1990, 1996 and 1999-2000 (record ends    in 2002), whilst at Ko&ecirc;s and Terra Rouge years of above average rainfall    are 1985-1988, 1999-2000, 2004-2006 and 2008-2010 (<a href="#f4">Fig. 4a</a>).    This indicates that there is a high level of inter-annual variability. When    a 5-year moving average is considered (<a href="#f4">Fig. 4b</a>), a wetter    phase is suggested from ~1971-1975 (slightly longer at Stampriet than Ko&ecirc;s/Terra    Rouge), a drier phase during the years ~1976-1985 and a second wetter phase    from the late 1990s until 2010. If the main control over chloride depth profiles    is climatic (wetter phases leading to lower chloride concentrations, and drier    phases leading to enriched chloride concentrations), we would expect to see    this reflected in the chloride fluctuations with depth, assuming piston flow.</font></p>     <p><a name="f4"></a></p>     ]]></body>
<body><![CDATA[<p>&nbsp;</p>     <p align="center"><img src="/img/revistas/wsa/v38n3/03f04.jpg"></p>     <p>&nbsp;</p>     <p><font face="Verdana, Arial, Helvetica, sans-serif" size="2">Plots of cumulative    chloride concentration against cumulative moisture content for each profile    are an effective way to examine the possibility of changing recharge rates and    environmental conditions (Allison et al., 1985; Scanlon, 1991; Cook et al.,    1992). Cumulative chloride concentration in place of depth makes it possible    to factor out variations in moisture content (Allison et al., 1985). <a href="#f5ab">Figure    5</a> indicates that in both KAL11/1 and KAL11/2 an upper region of higher recharge,    of 14 mmy<sup>-1</sup> and 18 mmy<sup>-1</sup>, respectively (taking input of    chloride to be 1.4 mgl<sup>-1</sup>), followed by lower recharge of 4 mmy<sup>-1</sup>    or 5 mmy<sup>-1</sup>, however without a similar recharge trend at the base,    with a higher rate in KAL11/1 than KAL11/2. Considering these profiles (profile    ages of 25 years for KAL11/1 and 33 years for KAL11/2) in light of the rainfall    record for Koes and Terra Rouge, the upper part may reflect the recent 1990s    wet phase, whilst the middle sections may reflect the 8 drier years (19761984)    with particularly dry conditions between 1981 and 1984 (annual totals ranging    from 20 mmy<sup>-1</sup> to 79 mmy<sup>-1</sup>, around 100 mmy<sup>-1</sup>    less than the long-term average). The deviation in apparent recharge rates in    the lower parts of KAL11/1 and KAL11/2 (10 mmy<sup>-1</sup> or 3 mmy<sup>-1</sup>)    is harder to account for. In KAL11/3 and KAL11/4 the comparable higher rates    of recharge through the bulk of the profiles is readily apparent (and illustrates    the influence of higher concentrations of chloride in the surface mixing zone,    and basal zone on the slope of the line in these plots) (<a href="#f5cd">Fig.    5c</a>, <a href="#f5cd">d</a>). A period of high recharge over the past decade's    worth of these profiles makes sense in light of the relatively high rainfall    experienced over the SAB since the late 1990s (<a href="#f4">Fig. 4</a>).</font></p>     <p>&nbsp;</p>     <p><a name="f5ab"></a></p>     <p align="center"><img src="/img/revistas/wsa/v38n3/03f05ab.jpg">    <br>   <a name="f5cd"></a> <img src="/img/revistas/wsa/v38n3/03f05cd.jpg"></p>     <p>&nbsp;</p>     <p><font face="Verdana, Arial, Helvetica, sans-serif" size="2"><b>Comparison with    other chloride mass balance recharge estimates in the southern Kalahari</b></font></p>     ]]></body>
<body><![CDATA[<p><font face="Verdana, Arial, Helvetica, sans-serif" size="2">The profiles therefore    record evidence that significant direct recharge from rainfall is occurring    through these dunes, with long-term average values for profiles ranging from    7 mmy<sup>-1</sup> to 46 mmy<sup>-1</sup>. There are no other estimates for    direct recharge through the USZ using the CMB methodology above the SAB with    which to compare these estimates; however, work has been done in the eastern    Kalahari in Botswana (reported by Beekman et al., 1996b; Selaolo, 1998; De Vries    et al., 2000). De Vries et al. (2000) used a subset of these profiles to conclude    that the spatial pattern of recharge via direct pathway was only ~5mmy<sup>-1</sup>    in the eastern fringes and ~ lmm-y<sup>-1</sup> in the centre of the Kalahari.    However, the 10 profiles from the Letlhakeng-Bothapatlou area of Botswana considered    by Selaolo (1998) contain a similar range of recharge estimates as found here    for the SAB (0.8 mmy<sup>-1</sup> to 33.8 mmy<sup>-1</sup>). The 10 profiles    covered a range of geomorphological settings, including high areas (presumed    to be on the surface of dunes), palaeo-valleys and the floor of a pan (where    the highest recharge rate was calculated). In addition, it was suggested that    the recharge mechanism is compounded by preferential flow (up to 90% might be    preferential in some profiles) (Selaolo, 1998; De Vries et al., 2000). In contrast    to the Botswana sites, the 4 SAB cores sampled here consisted of sand cover    without the complication of dual porosity; we did not encounter calcrete layers    or variations in sediment texture that were found in eastern Botswana. There    are, however, limitations to these provisional estimates of recharge relating    to spatial variability (Edmunds and Gaye, 1994).</font></p>     <p><font face="Verdana, Arial, Helvetica, sans-serif" size="2"><b><i>Comparison    with other recharge rates estimated from other methods for the Stampriet Basin</i></b></font></p>     <p><font face="Verdana, Arial, Helvetica, sans-serif" size="2">Other estimates    for recharge for the SAB (and predominantly for the Kalahari Aquifer) come from    CMB work using the saturated zone (JICA, 2002). This uses the chloride concentration    in the saturated zone from groundwater itself (C ) in Eq. (1), instead of C<sub>s</sub>    (chloride content of soil). From the boreholes measured, a map of recharge distribution,    created by JICA (2002) suggests values of 0 mmy<sup>-1</sup> to 1 mmy<sup>-1</sup>    in the southern part of the basin and 1 mmy<sup>-1</sup> to 2 mmy<sup>-1</sup>    (with patches of 2 mmy<sup>-1</sup> to 5 mmy<sup>-1</sup>) in the northern part    of the basin. We note here that the use of CMB in the saturated zone is complicated    by the fact that the groundwater-chloride concentrations are almost certainly    a mixed signature from the unsaturated zone inputs and from any lateral flow    of groundwater in the basin (in this case lateral flow from NW to SE in the    confined Auob Aquifer, following the piezometric surface), which may relate    to different input times and conditions. Saturated zone values can provide <i>minimum</i>    recharge values, but true present-day values will almost certainly be higher    due to geological inputs (evaporite dissolution, mixing with older formation    waters, etc.). Any geological inputs via the USZ on the other hand are immediately    recognisable through sustained higher chloride signatures with depth.</font></p>     <p><font face="Verdana, Arial, Helvetica, sans-serif" size="2">In addition, isotopes    of oxygen and hydrogen from borehole groundwater were analysed by JICA (2002)    and compared to a local meteoric water line, which gave a crude estimate of    2 mmy<sup>-1</sup> to 7 mmy<sup>-1</sup>. However, it was noted that the isotopic    signatures in groundwater are not straightforward, with kinetic effects and    non-equilibrium enrichment. 'JICA (2002) also looked directly at groundwater    levels in boreholes (mainly into the confines Auob aquifer unit), and saw an    increase (of up to 50 cm) after the exceptional 1999-2000 rainy season; whilst    in other years (considered by JICA (2002) to be average years) drawdown of ~5    cm was observed. Any measurements from water levels must also account for abstraction    rates, and factor these in to convert this information into data about recharge    rates.</font></p>     <p><font face="Verdana, Arial, Helvetica, sans-serif" size="2">Results for the    USZ recharge in the Stampriet Basin are in line with the recharge estimates    using chloride (and other isotopic tracers) in other semi-arid regions. For    example, in Senegal the long-term average recharge near Louga was estimated    to be 30 mmy<sup>-1</sup> (~10% of the average precipitation of 290 mmy<sup>-1</sup>)    (Gaye and Edmunds, 1996). In the Manga Grasslands of Nigeria the recharge rate    was estimated to be 44 mmy<sup>-1</sup>, whilst the regional pattern for NE    Nigeria was even higher (60 mm- y<sup>-1</sup>), where mean annual rainfall    is 434 mmy<sup>-1</sup> (Edmunds et al., 1999). Scanlon et al. (2006) reviews    applications of CMB to semi-arid areas, which illustrate a range of recharge    rates calculated from sand-rich profiles. The lowest value is 0.06 mm-y<sup>-1</sup>    (in a region covered by Mallee vegetation, Allison et al., 1990), whilst in    less vegetated areas magnitudes range from 1 mm-y<sup>-1</sup> to 94 mm-y<sup>-1</sup>.    By comparison, recharge rates in clay-rich sands are 0.5 mm-y<sup>-1</sup> to    24 mm-y<sup>-1</sup>; volcanic alluvium &lt; 0.01 mm-y<sup>-1</sup> to 9.9 mm-y<sup>-1</sup>;    streams 41 mm-y<sup>-1</sup> to 91 mm-y<sup>-1</sup>; and interfluvial areas    0.3 mmy<sup>-1</sup> to 5.8 mm-y<sup>-1</sup>.</font></p>     <p><font face="Verdana, Arial, Helvetica, sans-serif" size="2"><b>Contribution    of direct recharge to groundwater</b></font></p>     <p><font face="Verdana, Arial, Helvetica, sans-serif" size="2">The finding that    recent recharge rates are between 7 mmy<sup>-1</sup> and 46 mm-y<sup>-1</sup>    (or between ~4% and 20% of average rainfall) through the superficial Kalahari    sand dune cover suggests direct drainage into the Kalahari Aquifer underlying    the dunes (although there may be small areas where the Kalahari beds have been    eroded down to the Upper Rietmond Member, <a href="/img/revistas/wsa/v38n3/03f02.jpg">Fig. 2</a>).    The calcrete that is known to underlie the Kalahari beds in many places is karstified,    as are the interbedded congolomerates and other calcretes, with good examples    of sinkholes in the former where it is exposed on the Wiessrand and above the    Kalkrand Basalt (Christelis and Struckmeier, 2001; Tredoux et al., 2002). It    is suggested here that the calcrete layer may be similarly weathered and eroded    (and not necessarily continuous) between the superficial sand dune cover and    the Kalahari beds. This provides hydraulic continuity with the Kalahari Aquifer    through the dune cover. This provides the first evidence to support the inference    identified by Tredoux et al. (2002), on the basis of water-table fluctuations,    that recharge mechanisms other than focused recharge through the Weissrand calcrete    sinkholes have to be in operation in different parts of the basin, and particularly    where the sand cover thickens. From the provisional estimates made here it can    be suggested that comparable recharge rates are occurring for the vast (~80%)    portion of the basin that is covered in dune sand, although it is not possible    to ascertain to what extent this would only recharge the Kalahari Aquifer level,    or also feed to some extent into the artesian layers. Despite the detailed reinterpretation    of the geology of the region, the potential, and extent of, hydraulic connection    between the unconfined Kalahari Aquifer and the confined Auob Aquifer is incompletely    understood, with Tredoux et al. (2002) suggesting potential connectivity through    geological faults, but highlighting the importance of recharge in the north-western    and western regions where the Auob beds outcrop on the Weissrand.</font></p>     <p><font face="Verdana, Arial, Helvetica, sans-serif" size="2">Therefore, the    direct recharge rates calculated here are most relevant for the unconfined Kalahari    Aquifer and are an important indicator toward the assessment of the amount of    renewable resource in the region, and should be considered in any future assessments    of the water balance in the region. A hydrocensus in 2000 carried out by DWAF    (Namibian Department of Water Affairs) and JICA illustrated that 3 915 of 4    915 boreholes tap the Kalahari Aquifer, and that 65.5% of the total abstracted    water in the SAB comes from the Kalahari Aquifer, with a rate from the Kalahari    Aquifer of ~9.8 x10<sup>6</sup> m<sup>3</sup>y<sup>-1</sup> (DWAF/JICA, 2000).    That JICA (2002) study also concluded that present abstraction was exceeding    estimates of recharge, implying that current use was unsustainable. The major    use of water in the SAB is irrigation (46% of annual abstraction), with 38%    being used for stock watering and just 16% for domestic use. A groundwater simulation    model suggests that it would take &gt;50% reduction in irrigation uses in the    Stampriet Town region to stabilise current groundwater levels, and that if present    extraction rates are continued the resource could dry up by 2026 (JICA, 2002).    Schwartz (2006) has simulated the water balance of unsaturated soils and unconsolidated    sediments across Namibia using UNSAT-H, HELP3 and MACRO4.3 to estimate pore-water    residence time as a tool for inferring the intrinsic vulnerability of the aquifer.    The SAB USZ estimates for pore-moisture age produced here for the 12 m depth    of dunes allows a comparison with calculations made by Schwartz (2006) for sand    (Schwartz's Unit Type 4), and suggests that his estimates of 200 year to &gt;500    year residence times for the USZ may be an overestimate. It is recommended that    further ground-truthing work is needed to close the gap between modelling and    field approaches.</font></p>     <p>&nbsp;</p>     <p><font face="Verdana, Arial, Helvetica, sans-serif" size="3"><b>Conclusion</b></font></p>     ]]></body>
<body><![CDATA[<p><font face="Verdana, Arial, Helvetica, sans-serif" size="2">Direct recharge    through the Kalahari dune unsaturated zone (uppermost part of the unsaturated    zone) is shown for the first time to be significant for the Stampriet Basin    through the first application of the chloride mass balance approach.</font></p>     <p><font face="Verdana, Arial, Helvetica, sans-serif" size="2">This indicates    potentially substantial recharge of between 7 mmy<sup>-1</sup> and 46 mmy<sup>-1</sup>    for the 4 studied dune profiles (9 m to 11.5 m in depth), representing conditions    over the past 13 to 33 years. The cores come from 2 regions of the basin, with    2 cores from dunes in the south-western portion (between Koes and Mata-Mata)    and neighbouring cores taken from a dune just east of Stampriet in the central    part of the basin. The level of variability in recharge rates between these    4 cores accords with the spatial variability observed using this technique in    many other semi-arid region unsaturated zones across the world (see those reviewed    in Scanlon et al., 2006). The chloride mass balance technique in the unsaturated    zone has the potential to further constrain the spatial variability of (and    the potential influence of different geomorphological conditions on) recharge    rates and calculate a regional average recharge rate for a wider portion of    this basin. This methodology will provide insights into regions of the basin,    especially those parts with sand cover, for which very little is known about    recharge, or is possible to determine using conventional water balance approaches.    Building on these reconnaissance profiles we plan to sample at other sites to    make an assessment of the regional-scale recharge pattern and potential variation    in different geomorphological settings and under different levels of vegetation    cover. This will also allow us to be able to compare the results obtained during    different years of sampling, noting the high levels of precipitation before    sampling in 2011.</font></p>     <p><font face="Verdana, Arial, Helvetica, sans-serif" size="2">Investigations    into the direct recharge mechanism, such as this, are a vital part of improving    our understanding of the water balance of the multi-layer Stampriet Basin, and    being able to assess the sustainability of the groundwater resource. The direct    recharge mechanism is particularly relevant for the uppermost layer, the Kalahari    Aquifer, which is overlain by dunefield sands in ~80% of the basin. Recharge    rates should also be calculated through the sand cover in the interdune areas    as part of this continuing research. This research is important, not least because    it is the Kalahari Aquifer that is most heavily utilised for water, with an    estimated 66% of abstraction from this layer of the aquifer (JICA, 2002), and    with regional variation in the proportion of water abstracted from the different    levels; this results in an even greater importance of the Kalahari Aquifer in    some regions. The research findings presented here complement the recent developments    in the understanding of recharge to the artesian Auob Aquifer in the north-western    and western portions of the basin via karst features and fault structures (Tredoux    et al., 2002). A combination of these approaches allows us to continue to address    the challenge of constraining recharge mechanisms in this important transboundary    basin.</font></p>     <p>&nbsp;</p>     <p><font face="Verdana, Arial, Helvetica, sans-serif" size="3"><b>Acknowledgements</b></font></p>     <p><font face="Verdana, Arial, Helvetica, sans-serif" size="2">This research is    supported by the Royal Geographical Society, Thesiger-Oman International Fellowship,    and research grant from the British Society for Geomorphology. The research    was carried out under research/collecting permit 1524/2010, issued by the Ministry    of Environment and Tourism, Namibia, to whom the authors are grateful. AECS    would like to thank Greg Christelis for his interest in this research and discussions    about the Stampriet Artesian Basin. Pieter M&ouml;ller and the De Waal family    are thanked for their permission to take samples on their land and for their    hospitality. Professor David Thomas is thanked for his academic support and    assistance in the field, Dr Christine Lane for field assistance, and Dr Mona    Edwards for her support in the laboratory.</font></p>     <p>&nbsp;</p>     <p><font face="Verdana, Arial, Helvetica, sans-serif" size="3"><b>References</b></font></p>     <!-- ref --><p><font face="Verdana, Arial, Helvetica, sans-serif" size="2">ADAMS S, TITUS    R and XU Y (2004) Groundwater Recharge Assessment of the Basement Aquifers of    Central Namaqualand. WRC Report No. 1093/1/04. 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