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Journal of the Southern African Institute of Mining and Metallurgy

versão On-line ISSN 2411-9717
versão impressa ISSN 2225-6253

J. S. Afr. Inst. Min. Metall. vol.111 no.4 Johannesburg Abr. 2011

 

JOURNAL PAPER

 

Sensitization behaviour of 11-12% Cr AISI 409 stainless steel during low heat input welding

 

 

C.J. van Niekerk; M. du Toit

University of Pretoria

 

 


SYNOPSIS

The study comprised of the investigation into the sensitization characteristics of AISI 409 titanium stabilized ferritic stainless steel during low heat input welding. AISI 409 is a fully ferritic stainless steel used in catalytic converters and tubing for automotive exhaust systems due to the supposition that sensitization does not occur during low heat input welding. Two plates of 2 and 4 mm were tested for sensitization during low heat input welding. The study confirmed that chromium carbide (M23C6) precipitation occurs on the grain boundaries in the heat-affected zone with consequent depletion of Cr adjacent to the grain boundaries during welding. In the 2 mm plate sensitization occurred in the heat input range of 0.1 kJ/mm to above 0.25 kJ/mm and in the 4 mm plate sensitization occurred in the heat input range of 0.2 to 0.9 kJ/mm. Ti stabilization is ineffective at the heat inputs used in this investigation due to the rapid cooling rate through the temperature region where TiC precipitates. The presence of N was found to be detrimental since it consumes Ti on cooling, forming TiN, effectively lowering the amount of Ti available for TiC formation during rapid cooling after welding. Annealing for 5 minutes at 725°C does not improve the sensitization characteristics of the welded plate. There is a linear increase in grain size as heat input increases. The resistance to pitting corrosion decreases in the sensitized, welded plate in the heat-affected zone adjacent to the fusion line of welding.

Keywords: AISI 409 ferritic stainless steel, sensitization, grain growth, resistance to pitting corrosion, low heat input welding


 

 

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References

1. CS409-Technical Data. Technical Manual published by Columbus Stainless. 2010.         [ Links ]

2. KIM, J.K., KIM, Y.H., UHMB, S.H., LEE, J.S., and KIM, K.Y. Intergranular corrosion of Ti-stabilized 11 wt% Cr ferritic stainless steel for automotive exhaust systems. Graduate Institute of Ferrous Technology, Pohang University of Science and Technology, Pohang, Korea, 2009.         [ Links ]

3. FOLKHARD, E. Welding Metallurgy of Stainless Steels. Springer-Verlag, Vienna, vol. 3, no. 11, 1988, pp. 34-35.         [ Links ]

4. LESLIE. The Physical Metallurgy of Steels. McGraw-HILL, 1983, p. 326, 341.         [ Links ]

5. GROBLER, C. Weldability studies on 12% and 14% chromium steels. PhD dissertation, University of Pretoria, South Africa, 1987.         [ Links ]

6. KIM, J.K., KIM, Y.H., LEE, J.S., and KIM, K.Y. Effect of chromium content on intergranular corrosion and precipitation of Ti-stabilized ferritic stainless steel. Graduate Institute of Ferrous Technology, Pohang University of Sciences and Technology, Pohang, Korea, 2010.         [ Links ]

7. TULING, A. EELS study of sensitization in 12% chromium steel. Proceedings of the Microscopy Society of Southern Africa 31, 2001, p. 26.         [ Links ]

8. GREEFF, M.L. The influence of welding parameters on the sensitization behaviour of 3CR12.MSc thesis. University of Pretoria, South Africa, 2005.         [ Links ]

9. LO, K.H., SHEK, C.H., and LAI, J.K.L. Recent developments in stainless steels. University of Hong Kong, Hong Kong, China, 2009.         [ Links ]

10. MESSLER, R.W. Jr. Principles of Welding. Wiley-VCH, 2004, pp. 550, 560-561, 563.         [ Links ]

11. WILLIAMS, J.G., and BARBARO, F.J. Susceptibility and Prevention of Weld HAZ Sensitization and Intergranular Stress Corrosion Cracking in Various 12% Cr steels. Australasian Welding Journal vol. 50(4th quarter), 2005, pp. 34-47.         [ Links ]

12. DU TOIT, M., VAN ROOYEN, G.T., and SMITH, D. An overview of the heataffected zone sensitization and stress corrosion cracking behaviour of 12% chromium type 1.4003 ferritic stainless steel. Corrosion, vol. 63, no. 5, 2005.         [ Links ]

13. VAN WARMELO, M., NOLAN, D., and NORRISH, J. Mitigation of sensitization effects in ustabilised 12%Cr ferritic stainless steel welds. Faculty of Engineering, University of Wollongong, Australia, 2007.         [ Links ]

14. GREEFF, M.L. and DU TOIT, M. Looking at the sensitization of 11-12% chromium EN 1.4003 stainless steels during welding. Welding Journal, vol. 85, no. 11, 2006, pp. 243s-251s.         [ Links ]

15. EASTERLING, K. Introduction to the Physical Metallurgy of Welding. 2nd Edition, Butterworth-Heinemann, 1992, p. 19.         [ Links ]

16. ASTM A 763 - 93. Standard Practices for Detecting Susceptibility to Intergranular Attack in Ferritic Stainless Steels. ASTM International, 2004.         [ Links ]

17. ASTM E 112 - 96. Standard Test Methods for Determining Average Grain Size. ASTM International, 2004.         [ Links ]

18. ASTM G 150 - 99. Standard Test Method for Electrochemical Critical Pitting Temperature Testing of Stainless Steels. ASTM International, 2004.         [ Links ]

19. ROSENTHAL, D. The theory of moving sources of heat and its application to metal treatments. Transactions of the AIME 68, 1946, pp. 849-866.         [ Links ]

20. PARDO, A., MERINO, M.C., COY, A.E., VIEJO, F., CARBONERAS, M. and ARRABAL, R. Influence of Ti, C and N concentration on the intergranular corrosion behaviour of AISI 316Ti and 321 stainless steels. Departamento de Ciencia de Materiales, Facultad de Ciencias Químicas, Universidad Complutense de Madrid, Madrid, Spain, 2007.         [ Links ]

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