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South African Journal of Chemistry

versão On-line ISSN 1996-840X
versão impressa ISSN 0379-4350

S.Afr.j.chem. (Online) vol.65  Durban  2012

 

RESEARCH ARTICLE

 

Ionic liquid 3-methyl-1-sulphonic acid imidazolium chloride {[Msim]Cl}: A highly efficient, mild and green catalyst for the synthesis of β-acetamido ketones

 

 

Abdolkarim ZareI, *; Tahereh Hekmat-ZadehI; Setareh Mirzaei-MonfaredII; Maria MerajoddinI; Hossein Torabi-MonfaredI; Mohammad Ali ZolfigolIII, *; Ahmad Reza Moosavi-ZareIII; Esmael RostamiI; Mohammad MokhlesiIII; Fatemeh Derakhshan-PanahIII; Saeedeh PorbahiI; Samira BalandehI

IDepartment of Chemistry, Payame Noor University, P.O. Box 19395-4697, Tehran, Iran
IIDepartment of Chemistry, Yasouj University, Yasouj, 75914-35, Iran
IIIFaculty of Chemistry, Bu-Ali Sina University, Hamedan, 6517838683, Iran

 

 


ABSTRACT

Bronstedacidic ionic liquid 3-methyl-1-sulphonic acid imidazolium chloride {[Msim]Cl} is utilized as a highly efficient, inexpensive, mild and green catalyst for the synthesis of β-acetamido ketones by the one-pot multi-component coupling between acetophenones, arylaldehydes, acetonitrile and acetyl chloride at room temperature. Under these conditions, the title compounds are produced in high to excellent yields and in relatively short reaction times. In addition, this method is superior to reported methods, for the synthesis of β-acetamido ketones and is applicable for the synthesis of tris(β-acetamido ketone).

Keywords: 3-Methyl-1-sulphonic acid imidazolium chloride {[Msim]Cl}, β-acetamido ketone, Bronsted acidic catalyst, ionic liquid, one-pot multi-component reaction, acetophenone


 

 

Full text available only in PDF format.

 

Acknowledgements

The authors gratefully acknowledge financial support of this work by the Research Affairs Office of Payame Noor University andBu-Ali Sina University (Grant number 32-1716 entitled development of chemical methods, reagents and molecules), and Center of Excellence in Development of Chemical Method (CEDCM), Hamedan, Iran.

 

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Received 17 January 2012
Revised 30 January 2012
Accepted 14 March 2012

 

 

* To whom correspondence should be addressed. E-mail: abdolkarimzare@yahoo.com or mzolfigol@yahoo.com

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