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South African Journal of Chemistry
versão On-line ISSN 1996-840X
versão impressa ISSN 0379-4350
S.Afr.j.chem. (Online) vol.62 Durban 2009
RESEARCH ARTICLE
Solid silica-based sulphonic acid as an efficient green catalyst for the selective oxidation of sulphides to sulphoxides using NaCIO in aqueous media
Ali Amoozadeh; Firouzeh Nemati
Department of Chemistry, Faculty of Science, Semnan University, Semnan, Iran
ABSTRACT
A range of sulphides can be selectively oxidized to the corresponding sulphoxides in good yields using NaClO/silica sulphonic acid as an efficient and recyclable solid acid catalyst, in both water and 50/50 water/EtOH as solvents. The new method compares favourably with previous methods in the literature.
Key words: Silica sulphonic acid, heterogeneous catalyst, oxidation, sulphides, sulphoxides
Full text available only in PDF format.
Acknowledgement
We thank the Department of Chemistry of Semnan University for supporting this work.
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Received 21 October 2008
Revised 6 December 2008
Accepted 7 January 2009
* To whom correspondence should be addressed. E-mail: aliamoozadeh@yahoo.com