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South African Journal of Chemistry

On-line version ISSN 1996-840X
Print version ISSN 0379-4350

S.Afr.j.chem. (Online) vol.61  Durban  2008

 

RESEARCH ARTICLE

 

Silica sulphuric acid as an efficient catalyst for the catalytic and metal-free oxidation of aromatic amines to their corresponding nitro compounds with sodium perborate under micellar media

 

 

Davood Habibi*; Mohammad A. Zolfigol; Maliheh Safaiee

Faculty of Chemistry, Bu-Ali Sina University, Hamedan 6517838683, Iran

 

 


ABSTRACT

Electron-donating substituted anilines were converted to their corresponding nitro compounds with sodium perborate in the presence of a catalytic amount of silica sulphuric acid under micellar media in moderate to good yields.

Keywords: Sodium perborate, nitro compounds, silica sulphuric acid, oxidation of anilines


 

 

Full text available only in pdf format.

 

Acknowledgement

The authors gratefully acknowledge financial support from the Bu-Ali Sina University, Hamedan, Iran.

 

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Received 6 December 2007
Revised 21 April 2008
Accepted 10 July 2008

 

 

* To whom correspondence should be addressed. E-mail: davood.habibi@gmail.com

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