Resumo

DU, R. et al. Study of the pyrolysis kinetics of Datong coal using a sectioning method. J. S. Afr. Inst. Min. Metall. [online]. 2016, vol.116, n.2, pp.201-208. ISSN 2411-9717.  http://dx.doi.org/10.17159/2411-9717/2016/v116n2a11.

Lump coals are currently employed to replace part of coke in the COREX melter-gasifier for ironmaking. In order to optimize the process, the pyrolysis kinetics of Datong coal used in the COREX process was studied. A sectioning method is proposed to overcome certain shortcomings of traditional methods for studying the pyrolysis of coal. Based on the sectioning method and the characteristics of the coal pyrolysis process, the temperature range was divided into three intervals. In the first, the adsorbed gas and water of crystallization were removed; in the second, the coal was transformed into semi-coke; and finally, the semi-coke was further coked. Three models of reaction were then established to study the different stages of the pyrolysis process: an interfacial chemical reaction model, a random pore model, and internal diffusion with shrinking volume. The results showed that the experimental data fitted the models well, with all correlation coefficients (r²) exceeding 0.97. Finally, the mechanisms of reaction and kinetic parameters for each temperature range were derived, which laid a necessary foundation for optimizing the usage of non-coking coal in the COREX process.

Palavras-chave : ironmaking; COREX process; kinetics; coal pyrolysis; sectioning method.

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