Resumo

CAN, N.  e  ERIC, R. Hurman. Titanium carbide-silicon nitride reactions at high temperature. J. S. Afr. Inst. Min. Metall. [online]. 2015, vol.115, n.12, pp.1215-1220. ISSN 2411-9717.  http://dx.doi.org/10.17159/2411-9717/2015/v115n12a10.

The kinetics and mechanism of the chemical interaction between silicon nitride and titanium carbide were investigated using thermogravimetric analysis (TGA). The samples were reacted isothermally at temperatures between 1600°C and 1700°C under nitrogen and argon atmospheres. The extent and rate of reaction increased with increasing temperature under both atmospheres; however, both the extent and rate were higher under argon. Silicon nitride, in the presence of titanium carbide, was thermally stable under nitrogen and the reactions were confined to Si₃N₄/TiC and TiC/N₂ interfaces. Under argon atmosphere silicon nitride dissociated completely to liquid silicon and nitrogen gas within about four hours of reaction time, depending on temperature, and a different reaction mechanism prevailed. The kinetics of interaction between silicon nitride and titanium carbide under nitrogen atmosphere was found to be controlled by the rate of diffusion of nitrogen into the titanium carbide/carbonitride phase. Under argon atmosphere the rate was found to be controlled by the rate of dissociation of silicon nitride. For both cases the mechanisms of reactions were determined in detail and then modelled.

Palavras-chave : silicon nitride; composite materials; densification; titanium carbide.

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