Abstract

DU PREEZ, A.C.  and  KOTZE, M.H.. Evaluation of a Versatic 10 acid/Nicksyn™ synergistic system for the recovery of nickel and cobalt from a typical lateritic leach liquor. J. S. Afr. Inst. Min. Metall. [online]. 2014, vol.114, n.5, pp.375-381. ISSN 2411-9717.

Mintek has been involved in extensive test work since the early 1990s on the recovery of nickel and cobalt from leach liquors saturated in calcium, using synergistic solvent extraction systems. During this period the Nicksyn™ reagent was developed, optimized, commercially manufactured, and tested by Tati Nickel on a demonstration plant for more than 2800 operating hours. Efficient recovery of nickel without the co-extraction of calcium, thus avoiding gypsum formation in the extraction and stripping circuits, was illustrated. This synergistic system was recently evaluated on a laboratory scale for the recovery of nickel and cobalt from synthetic lateritic sulphate leach liquor containing about 3 g/L nickel, 0.5 g/L cobalt, 0.7 g/L manganese, 20 g/L magnesium, and with calcium at saturation. Extraction and stripping parameters were determined for this feed liquor and are discussed in this paper.

Keywords : solvent extraction; nickel laterites; reagents; synergistic systems.