versão On-line ISSN 1816-7950
RAMMIKA, Modise; DARKO, Godfred e TORTO, Nelson. Incorporation of Ni(II)-dimethylglyoxime ion-imprinted polymer into electrospun polysulphone nanofibre for the determination of Ni(II) ions from aqueous samples. Water SA [online]. 2011, vol.37, n.4, pp. 539-546. ISSN 1816-7950.
Ni(II)-dimethylglyoxime ion-imprinted polymer (Ni(II)-DMG IIP) was encapsulated in polysulphone and electrospun into nanofibres with diameters ranging from 406 to 854 nm. The structures of the Ni(II)-DMG encapsulated-IIP nanofibre, non-imprinted encapsulated-polymer nanofibre and polysulphone nanofibre mats were observed by scanning electron microscopy and evaluated by infrared spectroscopy. Electrospinning increased the specific surface area of the Ni(II)-DMG encapsulated-IIP nanofibre mats, as was evidenced by the low masses of the Ni(II)-DMG encapsulated-IIP nanofibre mats used. The accuracy of the method was validated by analysing a custom solution of certified reference material (SEP-3); the concentration of Ni(II) obtained was close to the certified one. The limit of detection was found to be 4.0x10-4 µg·mℓ-1 while the limit of quantification was found to be 1.2x10-3 µg·mℓ-1. The recovery of Ni(II) achieved using the Ni(II)-DMG imprinted nanofibre mats in water samples was found to range from 83 to 89%, while that of non-imprinted nanofibre mats was found to range from 59 to 65%, and that of polysulphone from 55 to 62%.
Palavras-chave : electrospun encapsulated imprinted polymer nanofibres; aqueous samples; recovery.