Resumo

DUGGAN, Andrew R.; MCITEKA, Lulama P.; LOBB, Kevin A.  e  KAYE, Perry T.. ¹H NMR-based kinetic-mechanistic study of the intramolecular trans-esterification of 2-exo-3-exo-dihydroxybornane monoacrylate esters. S.Afr.j.chem. (Online) [online]. 2013, vol.66, pp.00-00. ISSN 1996-840X.

A ¹H NMR study of the acid-catalyzed, intramolecular trans-esterification between isomeric 2-exo-3-exo-dihydroxybornane monoacrylate esters has afforded insights into the reaction mechanism and permitted the determination of kinetic and thermodynamic parameters for the pseudo-first-order processes.

Palavras-chave : Trans-esterification; kinetics; dihydroxybornane monoacrylate esters; ¹H NMR studies.

        · texto em Inglês     · Inglês ( pdf )