Abstract

BOOYSEN, Irvin N. et al. Oxo and oxofree rhenium(V) complexes with N,O-donor Schiff bases. S.Afr.j.chem. (Online) [online]. 2012, vol.65, pp.174-177. ISSN 1996-840X.

The reaction between cis-[Re^VO₂I(PPh₃)₂] and H₃duo (N-(2-hydroxybenzylidene)-5-amino-1,3-dimethyl uracil) led to the formation of the oxofree, imido compound, trans-[Re^V(ddd)(Hduo)(PPh₃)₂]I (1) (H₂ddd = 5,6-diamino-1,3-dimethyluracil). An oxo complex, cis-[Re^V(bcp)OCl₂(PPh₃)](2) [Hbcp = N-(2-hydroxybenzylidene)-benzothiazole] was isolated from the reaction of trans-[ReO^VCl₃(PPh₃)₂]with Hbcp. The crystal structures of the compounds were determined by single crystal X-ray diffraction.

Keywords : Rhenium(V); imido; oxo; crystal structure; spectral characterization.

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