Abstract

YELWANDE, Ajeet A.; ARBAD, Balasaheb R.  and  LANDE, Machhindra K.. Polyaniline/SiO₂ catalyzed one-pot synthesis of tetrahydrobenzo[b]pyran derivatives. S.Afr.j.chem. (Online) [online]. 2010, vol.63, pp.199-203. ISSN 1996-840X.

Polyaniline/SiO₂ is an efficient catalyst for the synthesis of tetrahydrobenzo[b]pyran derivatives from a one-pot, three component, condensation of aldehydes, malononitrile and dimedone at room temperature. This protocol has several advantages such as high yield, a simple work up procedure, low toxicity and easy recovery and reusability of the catalytic material. The catalyst has been readily prepared and characterized by means of thermal analysis (TG-DTA), X-ray diffraction (XRD), scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FT-IR).

Keywords : Chemical oxidative method; Polyaniline/SiO₂; tetrahydrobenzo[b]pyran.

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