Water SA

A feasibility study of in-line rheological characterisation of a wastewater sludge using ultrasound technology

The rheological characteristics of sludge affect transportation, treatment and the disposal processes involved in sludge system design and management operations such as dewatering, including flocculation and filtration. The concentration of solid matter in the sludge has an effect on rheological parameters such as yield stress and viscosity. These rheological properties of sludge are almost exclusively obtained today using commercially available instruments, such as conventional rotational rheometers or tube (capillary) viscometers. Since these methods are time-consuming and unsuitable for realtime process monitoring, the ultrasonic velocity profiling coupled with pressure drop (UVP+PD) methodology becomes very attractive for in-line flow behaviour monitoring for quality control and process optimisation. The main objective of this research work was to evaluate the UVP+PD technique in a concentrated sludge as found in a wastewater treatment plant. A portable pump test rig with tube viscometer fitted with a UVP+PD system was used to determine the rheological parameters. Conventional UVP installation techniques were tested as well as a new delay line UVP transducer. The results obtained from different installation techniques and transducers are compared. Finally, rheological parameters obtained using UVP+PD compared within 15% of that obtained using the tube viscometer. The results showed that UVP+PD is a feasible and promising technique for in-line real time flow visualisation and rheological characterisation for treated wastewater sludge which, when used as in-line process control, could lead to significant savings in chemicals and will optimise processes producing drier sludges and filter cakes.

Rainfall intensity effects on crusting and mode of seedling emergence in some quartz-dominated South African soils

Predicted changes in rainfall intensity due to climate change are likely to influence key soil health parameters, especially structural attributes and crop growth. Variations in rainfall intensity will impact crop production negatively. It is therefore imperative to investigate the interaction between predicted increases in rainfall intensity and key soil health parameters, particularly in relation to soil structural attributes and plant growth. The objectives of this study were to determine the effects of rainfall intensity on soil crust formation and mode of seedling emergence in soils dominated by primary minerals. Soil samples were collected from the top 200 mm, air dried and then packed uniformly into plastic pots, which were perforated at the bottom. Three maize seeds of equal size were planted in a triangular pattern in each pot at a depth of 30 mm, after which the pots were pre-wetted by capillary. The samples were then subjected to simulated rainfall at 3 intensities, i.e., 30, 45 and 60 mm/h, for 5 min. Rainfall intensity significantly (P < 0.05) affected crust strength and mean emergence day (MED), but not emergence percentage (EMP) and shoot length (P > 0.05). The 60 mm/h rainfall intensity resulted in the highest crust strength and MED. The strength of crust for all three rainfall intensities was influenced by quartz content, soil organic matter, clay and hematite. Most seedlings emerged through cracks, which resulted in rainfall intensity having no significant effects on seedling EMP and shoot length. We concluded that any increase in rainfall intensity is likely to increase the severity of crusting in these soils. However, soils with extensive cracking are likely to have higher EMP and lower MED and more vigorous seedlings despite the strength of the crust. As a result, post-planting tillage methods that enhance crust cracking may be employed to enhance seedling emergence and growth in these soils.

Analytical solutions for the recovery tests after constant-discharge tests in confined aquifers

A new analytical solution for residual drawdown during the recovery period after a constant rate pumping test is described. A comparison between the proposed solution, existing solutions and experimental data from field observation are presented. The proposed analytical solution is in perfect agreement with the experimental data for α = 0.01, in contrast to the Cooper-Jacob solution. A new analytical solution for the determination of the skin factor without any restriction on the variables t and t' is derived. An analytical solution for the drawdown response in a confined aquifer that is pumped step-wise or intermittently at a different discharge rate is suggested. On the basis of the suggested solution, a new analytical solution for the analysis of residual drawdown data after a pumping test with step-wise or intermittently changing discharge rates is provided.

Synthesis of bulk ion-imprinted polymers (IIPs) embedded with oleic acid coated Fe₃O₄ for selective extraction of hexavalent uranium

ABSTRACT A selective and reliable method for the extraction of trace quantities of U(VI) by the use of a magnetic U(VI) ion-imprinted polymer (IIP) was developed. In this study, oleic acid (OA) coated magnetite nano-particles were incorporated into the cross-linked polymeric matrix of the selective sorbent, in order to gain the physical advantages of separating the polymers. Many physico-chemical factors influence the adsorption process; uranyl ion uptake ability based on these parameters was investigated. The optimum parameters obtained were sample pH 4, 50 mg of the magnetic polymer, a contact time of 45 min and an initial U(VI) concentration of 2 mg ℓ-1. The adsorption capacities for the magnetic NIP and IIP were found to be 0.95 mg-g¹ and 1.21 mg-g-1, respectively. The adsorption behaviour of U(VI) in the presence of other competing metal ions onto the cross-linked magnetic polymers was also examined in binary mixtures and the order of selectivity was found to be U(VI) > Pb(VI) > Ni(II). The resulting magnetic nano-composite polymers were found to be stable up to the sixth cycle of use and reuse. The Freundlich adsorption model was used for the mathematical description of the adsorption equilibrium and the adsorption kinetic data fitted the pseudo-first-order model with R² > 0.92.

**Human health risk assessment for silver catfish Schilbe intermedius Rüppell, 1832, from two impoundments in the Olifants River, Limpopo, South Africa**

ABSTRACT As rural populations grow and rural poverty increases, consumption of fish from contaminated river systems will increase to supplement dietary protein requirements. The concentrations of metals in fish muscle tissue at two impoundments of the Olifants River (Flag Boshielo Dam and the Phalaborwa Barrage) were measured, and a human health risk assessment following Heath et al. (2004) conducted to investigate whether consumption of Schilbe intermedius from these impoundments posed a risk to human health. The results confirmed that metals are accumulating in the muscle tissue of S. intermedius. No patterns were observed in the ratios of the metals bio-accumulated at each impoundment. The human health risk assessment identified that all fish analysed exceeded the recommended levels for safe consumption for lead and chromium and about 50% exceeded the recommended level for antimony at Flag Boshielo Dam. Almost all fish analysed exceeded the recommended level for lead and more than 50% exceeded the recommended level for arsenic at the Phalaborwa Barrage. We conclude that weekly consumption of S. intermedius from these impoundments may pose an unacceptable risk to the health of rural communities.

SST prediction methodologies and verification considerations for dynamical mid-summer rainfall forecasts for South Africa

ABSTRACT Seasonal-to-interannual hindcasts (re-forecasts) for December-January-February (DJF) produced at a 1-month lead-time by the ECHAM4.5 atmospheric general circulation model (AGCM) are verified after calibrating model output to DJF rainfall at 94 districts across South Africa. The AGCM is forced with SST forecasts produced by (i) statistically predicted SSTs, and (ii) predicted SSTs from a dynamically coupled ocean-atmosphere model. The latter SST forecasts in turn consist of an ensemble mean of SST forecasts, and also by considering the individual ensemble members of the SST forecasts. Probabilistic hindcasts produced for two separate category thresholds are verified over a 24-year test period from 1978/79 to 2001/02 by investigating the various AGCM configurations' attributes of discrimination (whether the forecasts are discernibly different given different outcomes) and reliability (whether the confidence communicated in the forecasts is appropriate). Deterministic hindcast skill is additionally calculated through a range of correlation estimates between hindcast and observed DJF rainfall. For both probabilistic and deterministic verification the hindcasts produced by forcing the AGCM with dynamically predicted SSTs attain higher skill levels than the AGCM forced with statistical SSTs. Moreover, ensemble mean SST forecasts lead to improved skill over forecasts that considered an ensemble distribution of SST forecasts.

Diatoms as indicators of historical water quality: A comparison of samples taken in the Wemmershoek catchment (Western Province, South Africa) in 1960 and 2008

ABSTRACT Historical diatom records provide a means of retrospectively determining water quality and inferring ecological condition in rivers and streams. In this study we re-sampled sites originally sampled 48 years previously. We then determined the scores for the Biological Diatom Index (BDI) and the South African Diatom Index (SADI) for each dataset. The results revealed that the present day conditions in this relatively undisturbed locality were almost identical to those reflected by the samples collected half a century before. This illustrates the value of historical diatom data for the purposes of determining antecedent water quality.